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Photodriven Charge Accumulation and Carrier Dynamics in a Water‐Soluble Carbon Nitride Photocatalyst
C. Li, E. Hofmeister, I. Krivtsov, D. Mitoraj, C. Adler, R. Beranek, B. Dietzek
ChemSusChem 2021


pH-Dependent Structure of Block Copolymer Micelles Featuring a Polyampholyte Corona: A Combined Experimental and Theoretical Approach
Jonas Eichhorn, Yulia D. Gordievskaya, Elena Yu. Kramarenko, Alexei R. Khokhlov, and Felix H. Schacher
Macromolecules 2021, XXXX, XX, XXX-XXX

Characterizing photocatalysts for water splitting: from atoms to bulk and from slow to ultrafast processes

C. Kranz, M. Wächtler
Chem. Soc. Rev. 2021, 50, 1407-1437




Polymeric Carbon Nitride Coupled with a Molecular Thiomolybdate Catalyst: Exciton and Charge Dynamics in Light-Driven Hydrogen Evolution

A. Rajagopal, E. Akbarzadeh, C. Li, D. Mitoraj, I. Krivtsov, C. Adler, T. Diemant, J. Biskupek, U. Kaiser,  C. Im, M. Heiland, T. Jacob, C. Streb, B. Dietzek, R. Beranek
Sustain. Energy Fuels 2020, 4, 6085-6095.


Hybrid photoanodes for visible light-driven water oxidation: the beneficial and detrimental effects of nickel oxide cocatalyst

P. Longchin,  D. Mitoraj, O. Mendoza Reyes, C. Adler, N. Wetchakun, R. Beranek

J. Phys. Energy 2020, 2, 044001.



Optically Triggered Control of the Charge Carrier Density in Chemically Functionalized Graphene Field Effect Transistors
Z. Tang, A. George, A. Winter, D. Kaiser, C. Neumann, T. Weimann, A. Turchanin
Chem. - A Eur. J. 2020, 26 (29), 6473–6478.


Minimizing Side Product Formation in Alkyne Functionalization of Ruthenium Complexes by Introduction of Protecting Groups

P. Wintergerst, K. Witas, D. Nauroozi, M.-A. Schmid, E. Dikmen, S. Tschierlei, S. Rau
Zeitschrift für Anorg. und Allg. Chemie 2020, 646 (13), 842–848.


Role of MLCT States in the Franck–Condon Region of Neutral, Heteroleptic Cu(I)–4H-Imidazolate Complexes: A Spectroscopic and Theoretical Study
C. Müller, M. Schulz, M. Obst, L. Zedler, S. Gräfe, S. Kupfer, B. Dietzek
J. Phys. Chem. A 2020, 124 (33), 6607–6616.


On the Importance of Catalysis in Photocatalysis: Triggering of Photocatalysis at Well-Defined Anatase TiO2 Crystals through Facet-Specific Deposition of Oxygen Reduction Cocatalyst
C. Adler, D. Mitoraj, I. Krivtsov, R. Beranek
J. Chem. Phys. 2020, 152 (24), 244702.


Synthesis and Hydrogen Evolving Catalysis of a Panchromatic Photochemical Molecular Device
J. Habermehl, D. Nauroozi, M. Martynow, Y. E. Vilk, R. Beranek, J. Guthmuller, S. Rau
Sustain. Energy Fuels 2020, 4 (2), 619–624.


Organic Linkage Controls the Photophysical Properties of Covalent Photosensitizer–Polyoxometalate Hydrogen Evolution Dyads
Y. Luo, S. Maloul, P. Endres, S. Schönweiz, C. Ritchie, M. Wächtler, A. Winter, U. S. Schubert, C. Streb, B. Dietzek
Sustain. Energy Fuels 2020, 4 (9), 4688–4693.


The Metallic Traveler: Formate- and Photoinduced Regioselective Phenanthroline Deuterations via Reductively Activated RhCp* Centers
A. K. Mengele, S. Rau
Organometallics 2020, 39 (14), 2739–2748.


Electrochemical Delamination Assisted Transfer of Molecular Nanosheets
Z. Tang, C. Neumann, A. Winter, A. Turchanin
Nanoscale 2020, 12 (16), 8656–8663.


Polyampholytic Poly(Dehydroalanine) Graft Copolymers as Smart Templates for PH-Controlled Formation of Alloy Nanoparticles
J. B. Max, K. Kowalczuk, M. Köhler, C. Neumann, F. Pielenz, L. V. Sigolaeva, D. V. Pergushov, A. Turchanin, F. Langenhorst, F. H. Schacher
Macromolecules 2020, 53 (11), 4511–4523.


Direct Molecular-Level near-Field Plasmon and Temperature Assessment in a Single Plasmonic Hotspot
M. Richard-Lacroix, V. Deckert
Light Sci. Appl. 2020, 9 (1), 35.


Embedding Molecular Photosensitizers and Catalysts in Nanoporous Block Copolymer Membranes for Visible-Light Driven Hydrogen Evolution
I. Romanenko, A. Rajagopal, C. Neumann, A. Turchanin, C. Streb, F. H. Schacher
J. Mater. Chem. A 2020, 8 (13), 6238–6244.


Molecular Scylla and Charybdis: Maneuvering between PH Sensitivity and Excited-State Localization in Ruthenium Bi(Benz)Imidazole Complexes
A. K. Mengele, C. Müller, D. Nauroozi, S. Kupfer, B. Dietzek, S. Rau
Inorg. Chem. 2020, 59 (17), 12097–12110.

Sonochemical Hydrogen Production as a Potential Interference in Light-Driven Hydrogen Evolution Catalysis
I. Roger, S. Rau, C. Streb
ACS Omega 2020, 5 (33), 21250–21253.


Low-Energy Electron Irradiation Induced Synthesis of Molecular Nanosheets: An Influence of the Electron Beam Energy
C. Neumann, R. Wilhelm, M. Küllmer, A. Turchanin
Faraday Discuss. 2020, No. (accepted manuscript).


Photocatalytically Active Block Copolymer Hybrid Micelles from Double Hydrophilic Block Copolymers
A. Nabiyan, M. Schulz, C. Neumann, B. Dietzek, A. Turchanin, F. H. Schacher
Eur. Polym. J. 2020, 140, 110037.


Confined Growth of Porous Nitrogen-Doped Cobalt Oxide Nanoarrays as Bifunctional Oxygen Electrocatalysts for Rechargeable Zinc–Air Batteries
X. Wang, Z. Liao, Y. Fu, C. Neumann, A. Turchanin, G. Nam, E. Zschech, J. Cho, J. Zhang, X. Feng
Energy Storage Mater. 2020, 26, 157–164.


All-Electrochemical Nanocomposite Two-Electrode Setup for Quantification of Drugs and Study of Their Electrocatalytical Conversion by Cytochromes P450
V. V. Shumyantseva, T. V. Bulko, A. V. Kuzikov, R. A. Masamrekh, A. Y. Konyakhina, I. Romanenko, J. B. Max, M. Köhler, A. A. Gilep, S. A. Usanov, D. V. Pergushov, F. H. Schacher, L. V. Sigolaeva
Electrochim. Acta 2020, 336, 135579.


Tailored Protective Groups for Surface Immobilization of Ruthenium Dyes
S. Amthor, H. Braun, J. Gröne, D. Nauroozi, T. Jacob, S. Rau
Dalt. Trans. 2020, 49 (12), 3735–3742.


Cobaloxime-Based Double Complex Salts as Efficient and Versatile Catalysts for the Light-Driven Hydrogen Evolution Reaction
E. Hofmeister, J. Woo, T. Ullrich, L. Petermann, K. Hanus, S. Rau, A. Kahnt, M. von Delius
ChemRxiv 2020,.


Structure of Diethyl-Phosphonic Acid Anchoring Group Affects the Charge-Separated State on an Iridium(III) Complex Functionalized NiO Surface
R. A. Wahyuono, S. Amthor, C. Müller, S. Rau, B. Dietzek
ChemPhotoChem 2020, 4 (8), 618–629.


Bottom‐up Design of Bimetallic Cobalt–Molybdenum Carbides/Oxides for Overall Water Splitting
R. Liu, M. Anjass, S. Greiner, S. Liu, D. Gao, J. Biskupek, U. Kaiser, G. Zhang, C. Streb
Chem. – A Eur. J. 2020, No. 26, 4157–4164.


Yield—Not Only Lifetime—of the Photoinduced Charge-Separated State in Iridium Complex–Polyoxometalate Dyads Impact Their Hydrogen Evolution Reactivity
Y. Luo, S. Maloul, S. Schönweiz, M. Wächtler, C. Streb, B. Dietzek
Chem. - A Eur. J. 2020, 26 (36), 8045–8052.


Iron(0)-Mediated Stereoselective (3+2)-Cycloaddition of Thiochalcones via a Diradical Intermediate
P. Buday, P. Seeber, C. Zens, H. Abul-Futouh, H. Görls, S. Gräfe, P. Matczak, S. Kupfer, W. Weigand, G. Mloston
Chem. - A Eur. J. 2020, 26 (50), 11412–11416.


Top-down Synthesis of Polyoxometalate-like Sub-Nanometer Molybdenum-Oxo Clusters as High-Performance Electrocatalysts
R. Liu, K. Cao, A. H. Clark, P. Lu, M. Anjass, J. Biskupek, U. Kaiser, G. Zhang, C. Streb
Chem. Sci. 2020, 11 (4), 1043–1051.


Redox-Inactive Ions Control the Redox-Activity of Molecular Vanadium Oxides
S. Greiner, B. Schwarz, M. Ringenberg, M. Dürr, I. Ivanovic-Burmazovic, M. Fichtner, M. Anjass, C. Streb
Chem. Sci. 2020, 11 (17), 4450–4455.


Is Electron Ping-Pong Limiting the Catalytic Hydrogen Evolution Activity in Covalent Photosensitizer–Polyoxometalate Dyads?
Y. Luo, S. Maloul, M. Wächtler, A. Winter, U. S. Schubert, C. Streb, B. Dietzek
Chem. Commun. 2020, 56 (72), 10485–10488.


A 3d-Printed Composite Electrode for Sustained Electrocatalytic Oxygen Evolution
S. Liu, R. Liu, D. Gao, I. Trentin, C. Streb
Chem. Commun. 2020, 56 (60), 8476–8479.


Influence of Surface Ligands on Charge-Carrier Trapping and Relaxation in Water-Soluble CdSe@CdS Nanorods
M. Micheel, B. Liu, M. Wächtler
Catalysts 2020, 10 (10), 1143.


PC 2D-COS: A Principal Component Base Approach to Two-Dimensional Correlation Spectroscopy
J. Hniopek, M. Schmitt, J. Popp, T. Bocklitz
Appl. Spectrosc. 2020, 74 (4), 460–472.


Water‐Soluble Polymeric Carbon Nitride Colloidal Nanoparticles for Highly Selective Quasi‐Homogeneous Photocatalysis
I. Krivtsov, D. Mitoraj, C. Adler, M. Ilkaeva, M. Sardo, L. Mafra, C. Neumann, A. Turchanin, C. Li, B. Dietzek, R. Leiter, J. Biskupek, U. Kaiser, C. Im, B. Kirchhoff, T. Jacob, R. Beranek
Angew. Chemie Int. Ed. 2020, 59 (1), 487–495.


DNA Origami Meets Polymers: A Powerful Tool for the Design of Defined Nanostructures
N. Hannewald, P. Winterwerber, S. Zechel, D. Y. W. Ng, M. D. Hager, T. Weil, U. S. Schubert
Angew. Chemie Int. Ed. 2020, anie.202005907.


Dynamic Covalent Formation of Concave Disulfide Macrocycles Mechanically Interlocked with Single‐Walled Carbon Nanotubes
B. Balakrishna, A. Menon, K. Cao, S. Gsänger, S. B. Beil, J. Villalva, O. Shyshov, O. Martin, A. Hirsch, B. Meyer, U. Kaiser, D. M. Guldi, M. Delius
Angew. Chemie Int. Ed. 2020, 59 (42), 18774–18785.


Proton and Li-Ion Permeation through Graphene with Eight-Atom-Ring Defects
E. Griffin, L. Mogg, G. P. Hao, G. P. Hao, G. Kalon, G. Kalon, C. Bacaksiz, G. Lopez-Polin, G. Lopez-Polin, T. Y. Zhou, V. Guarochico, J. Cai, C. Neumann, A. Winter, M. Mohn, J. H. Lee, J. Lin, J. Lin, U. Kaiser, I. V. Grigorieva, K. Suenaga, B. Özyilmaz, H. M. Cheng, H. M. Cheng, W. Ren, A. Turchanin, F. M. Peeters, A. K. Geim, M. Lozada-Hidalgo
ACS Nano 2020, 14 (6), 7280–7286.



Intrinsic Electric Field-Induced Properties in Janus MoSSe van Der Waals Structures
F. Li, W. Wei, H. Wang, B. Huang, Y. Dai, T. Jacob
J. Phys. Chem. Lett. 2019, 10 (3), 559–565.


Homogeneous Visible Light-Driven Hydrogen Evolution by the Molecular Molybdenum Sulfide Model [Mo2S12]2−
A. Rajagopal, F. Venter, T. Jacob, L. Petermann, S. Rau, S. Tschierlei, C. Streb
Sustain. Energy Fuels 2019, 3 (1), 92–95.


Electrostatically Directed Assembly of Nanostructured Composites for Enhanced Photocatalysis
S. Kohsakowski, P. Pulisova, D. Mitoraj, S. Neubert, J. Biskupek, U. Kaiser, S. Reichenberger, G. Marzun, R. Beranek
Small Methods 2019, 3 (8), 1800390.


Polymer Brushes on Hexagonal Boron Nitride
W. Sheng, I. Amin, C. Neumann, R. Dong, T. Zhang, E. Wegener, W. Chen, P. Förster, H. Q. Tran, M. Löffler, A. Winter, R. D. Rodriguez, E. Zschech, C. K. Ober, X. Feng, A. Turchanin, R. Jordan
Small 2019, 15 (19), 1805228.


Long-Term Stable Poly(Ionic Liquid)/MWCNTs Inks Enable Enhanced Surface Modification for Electrooxidative Detection and Quantification of DsDNA
L. V. Sigolaeva, T. V. Bulko, M. S. Kozin, W. Zhang, M. Köhler, I. Romanenko, J. Yuan, F. H. Schacher, D. V. Pergushov, V. V. Shumyantseva
Polymer (Guildf). 2019, 168, 95–103.


Excited State Properties of a Series of Molecular Photocatalysts Investigated by Time Dependent Density Functional Theory
M. Martynow, S. Kupfer, S. Rau, J. Guthmuller
Phys. Chem. Chem. Phys. 2019, 21 (18), 9052–9060.


Selective Ion Sieving through Arrays of Sub-Nanometer Nanopores in Chemically Tunable 2D Carbon Membranes
P. M. G. van Deursen, Z. Tang, A. Winter, M. J. Mohn, U. Kaiser, A. A. Turchanin, G. F. Schneider
Nanoscale 2019, 11 (43), 20785–20791.


Micro-Structured Polydopamine Films via Pulsed Electrochemical Deposition
J. Lin, S. Daboss, D. Blaimer, C. Kranz
Nanomaterials 2019, 9 (2), 242.


The Reactivity and Stability of Polyoxometalate Water Oxidation Electrocatalysts
D. Gao, I. Trentin, L. Schwiedrzik, L. González, C. Streb
Molecules 2019, 25 (1), 157.


Towards Covalent Photosensitizer-Polyoxometalate Dyads-Bipyridyl-Functionalized Polyoxometalates and Their Transition Metal Complexes
A. Winter, P. Endres, E. Schröter, M. Jäger, H. Görls, C. Neumann, A. Turchanin, U. S. Schubert
Molecules 2019, 24 (24), 4446.


Different Routes to Ampholytic Polydehydroalanine: Orthogonal versus Simultaneous Deprotection
J. Kruse, P. Biehl, F. H. Schacher
Macromol. Rapid Commun. 2019, 40 (10), 1800857.


Effect of the Catalytic Center on the Electron Transfer Dynamics in Hydrogen-Evolving Ruthenium-Based Photocatalysts Investigated by Theoretical Calculations
M. Staniszewska, S. Kupfer, J. Guthmuller
J. Phys. Chem. C 2019, 123 (26), 16003–16013.


Promising Sensitizers for Dye Sensitized Solar Cells: A Comparison of Ru(II) with Other Earth’s Scarce and Abundant Metal Polypyridine Complexes
A. Sen, A. Groß
Int. J. Quantum Chem. 2019, 119 (16).


Impact of Alkyne Functionalization on Photophysical and Electrochemical Properties of 1,10-Phenanthrolines and Their Ru II Complexes
P. Wintergerst, A. K. Mengele, D. Nauroozi, S. Tschierlei, S. Rau
Eur. J. Inorg. Chem. 2019, 2019 (14), 1988–1992.


Stille Expands the Family: Access to 5,6-Bis-2-Thienyl-Substituted Phenanthroline Under Mild Conditions for Luminescent Ruthenium Complexes
J. Brückmann, A. A. Heidecker, D. Popovic, A. K. Mengele, D. Nauroozi, P. Bäuerle, S. Rau
Eur. J. Inorg. Chem. 2019, 2019 (13), 1832–1838.


Electrodeposition of Ag onto Au(111) from Deep Eutectic Solvents
M. U. Ceblin, S. Zeller, B. Schick, L. A. Kibler, T. Jacob
ChemElectroChem 2019, 6 (1), 141–146.


Unraveling the Light‐Activated Reaction Mechanism in a Catalytically Competent Key Intermediate of a Multifunctional Molecular Catalyst for Artificial Photosynthesis
L. Zedler, A. K. Mengele, K. M. Ziems, Y. Zhang, M. Wächtler, S. Gräfe, T. Pascher, S. Rau, S. Kupfer, B. Dietzek
Angew. Chemie Int. Ed. 2019, 58 (37), 13140–13148.


Selectivity of Chemical Conversions: Do Light‐Driven Photoelectrocatalytic Processes Hold Special Promise?
R. Beranek
Angew. Chemie Int. Ed. 2019, 58 (47), 16724–16729.


Modular Design of Noble‐Metal‐Free Mixed Metal Oxide Electrocatalysts for Complete Water Splitting
D. Gao, R. Liu, J. Biskupek, U. Kaiser, Y. Song, C. Streb
Angew. Chemie 2019, 131 (14), 4692–4696.


Poly(1,4‐Diethynylbenzene) Gradient Homojunction with Enhanced Charge Carrier Separation for Photoelectrochemical Water Reduction
H. Sun, C. Neumann, T. Zhang, M. Löffler, A. Wolf, Y. Hou, A. Turchanin, J. Zhang, X. Feng
Adv. Mater. 2019, 31 (19), 1900961.


Artificial Microbial Arenas: Materials for Observing and Manipulating Microbial Consortia
L. Wondraczek, G. Pohnert, F. H. Schacher, A. Köhler, M. Gottschaldt, U. S. Schubert, K. Küsel, A. A. Brakhage
Adv. Mater. 2019, 31 (24), 1900284.


Synergy of Photoinduced Force Microscopy and Tip-Enhanced Raman Spectroscopy—A Correlative Study on MoS2
R. Meyer, S. Trautmann, K. Rezaei, A. George, A. Turchanin, V. Deckert
ACS Photonics 2019, 6 (5), 1191–1198.


Revealing the Mechanism of Multiwalled Carbon Nanotube Growth on Supported Nickel Nanoparticles by in Situ Synchrotron X-Ray Diffraction, Density Functional Theory, and Molecular Dynamics Simulations
A. Gili, L. Schlicker, M. F. Bekheet, O. Görke, D. Kober, U. Simon, P. Littlewood, R. Schomäcker, A. Doran, D. Gaissmaier, T. Jacob, S. Selve, A. Gurlo
ACS Catal. 2019, 9 (8), 6999–7011.


Preparation of Carbon Nanomembranes without Chemically Active Groups
C. Neumann, M. Szwed, M. Frey, Z. Tang, K. Kozieł, P. Cyganik, A. Turchanin
ACS Appl. Mater. Interfaces 2019, 11 (34), 31176–31181.


Does Involving Additional Linker Always Increase the Efficiency of an Organic Dye for p -Type Dye-Sensitized Solar Cells?
A. Sen, A. Groß
ACS Appl. Energy Mater. 2019, 2 (9), 6341–6347.


Freestanding Carbon Nanomembranes and Graphene Monolayers Nanopatterned via EUV Interference Lithography
A. Winter, Y. Ekinci, A. Gölzhäuser, A. Turchanin
2D Mater. 2019, 6 (2), 021002.



Multi-Phase Real-Time Monitoring of Oxygen Evolution Enables in Operando Water Oxidation Catalysis Studies
F. L. Huber, S. Amthor, B. Schwarz, B. Mizaikoff, C. Streb, S. Rau
Sustain. Energy Fuels 2018, 2 (9), 1974–1978.



Hydrogen Evolution Catalysis by Molybdenum Sulfides (MoSx): Are Thiomolybdate Clusters like [Mo3S13]2− Suitable Active Site Models?
M.-L. Grutza, A. Rajagopal, C. Streb, P. Kurz
Sustain. Energy Fuels 2018, 2 (9), 1893–1904.



Understanding Homogeneous Hydrogen Evolution Reactivity and Deactivation Pathways of Molecular Molybdenum Sulfide Catalysts
M. Dave, A. Rajagopal, M. Damm-Ruttensperger, B. Schwarz, F. Nägele, L. Daccache, D. Fantauzzi, T. Jacob, C. Streb
Sustain. Energy Fuels 2018, 2 (5), 1020–1026.



Toward a Tunable Synthetic [FeFe]-Hydrogenase H-Cluster Mimic Mediated by Perylene Monoimide Model Complexes: Insight into Molecular Structures and Electrochemical Characteristics
H. Abul-Futouh, A. Skabeev, D. Botteri, Y. Zagranyarski, H. Görls, W. Weigand, K. Peneva
Organometallics 2018, 37 (19), 3278–3285.



Photochemical and Electrochemical Hydrogen Evolution Reactivity of Lanthanide-Functionalized Polyoxotungstates
M. Arab Fashapoyeh, M. Mirzaei, H. Eshtiagh-Hosseini, A. Rajagopal, M. Lechner, R. Liu, C. Streb
Chem. Commun. 2018, 54 (74), 10427–10430.



Manganese Vanadium Oxide–N-Doped Reduced Graphene Oxide Composites as Oxygen Reduction and Oxygen Evolution Electrocatalysts
X. Xing, R. Liu, K. Cao, U. Kaiser, G. Zhang, C. Streb
ACS Appl. Mater. Interfaces 2018, 10 (51), 44511–44517.

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